In the old days of crystal radio sets this effect was used to form the diode in the receiver. The "crystal" was a lump of something, can't remember the details now, with some impurities mixed into it. You scratched on the lump with a piece of wire,called a cats whisker, until you found a spot which gave you reception.
When valves/tubes were invented diodes became available and the need for the crystal and cats whisker fell away.
This is not first hand knowledge, I'm not that old, but we learnt a bit about the history of radio in Radio 101 at Technikon.
Keith