I think the main question you need to ask yourself, is do you have enough knowledge to be able to teach someone else. It's not so much about the steps of building a guitar, because those really are not that hard. It's about dealing with problems as they happen. With 5 or 6 students who have limited or no wood work experience there WILL be problem, heck even with experience guys there is always a chance for problems. An example is your post about how to deal with the bowed bookmatched. You now know how to deal with that, but if it happened during class to a student before this post, what would you have done? If a student routes something in the wrong place or has a bad chip out, what will you tell them to do to fix it? We all encouter problems along the way, experience is what helps us determine how to solve it. And you don't have much experience yet.
This is not really doubting your abilities to build, but just trying to get you to think about what you'll do when someone else has a problem. Do you have the knowledge to help them fix it? People will not be happy they are paying for a class and come in, make a mistake and are told they will have to wait until you can find an answer on a message board about how to fix it.
I work as an ice hockey referee and the last few years I work as an instructor at our yearly seminars. Teaching the material from the books and the slide shows is the easy part, and really anyone off the street could do it with no background knowledge. The difference is when people start asking questions about stuff that is not covered in the books and how to deal with problems, that is where experience comes in.
Bottom line is you have to ask yourself, do you have enough experience to handle problems when they occur?